Pairwise Assembly of Organopalladium(II) Units with Cyanurato(3−) and Trithiocyanurato(3−) Ligands: Formation of Chiral Pd12, Pd10, and Pd9 Cage-Molecules
نویسندگان
چکیده
The o-palladated, chloro-bridged dimers [Pd{2-phenylpyridine(-H)}-μ-Cl]2 and [Pd{N,N-dimethylbenzylamine(-H)}-μ-Cl]2 react with cyanuric acid in the presence of base to afford closed, chiral cage-molecules in which 12 organo-Pd(II) centers, located in pairs at the vertices of an octahedron, are linked by four tetrahedrally arranged cyanurato(3-) ligands. Incomplete (Pd10) cages, having structures derived from the corresponding Pd12 cages by replacing one pair of organopalladium centers with two protons, have also been isolated. Reaction of [Pd{2-phenylpyridine(-H)}-μ-Cl]2 with trithiocyanuric acid gives an entirely different and more open type of cage-complex, comprising only nine organopalladium centers and three thiocyanurato(3-) ligands: cage-closure in this latter system appears to be inhibited by steric crowding of the thiocarbonyl groups.
منابع مشابه
Diamondoids and DNA Nanotechnologies
Diamondoids are cage-like saturated hydrocarbons consisting of fused cyclohexane rings. The Diamondoids family of compounds is one of the best candidates for molecular building blocks (MBBs) in nanotechnology to construct organic nanostructures compared to other MBBs known so far. The challenge is to find a route for self-assembly of these cage hydrocarbons and their applications in the bottom-...
متن کاملExpression of insulin-like peptide 3 in the postnatal rat Leydig cell lineage: timing and effects of triiodothyronine-treatment.
Fetal (FLC) and adult Leydig cells (ALC) secrete insulin-like peptide 3 (INSL3), which is linked to cryptorchidism in the newborn rat. Its gene regulation appears to be independent of that for most steroidogenic enzymes, and may thus be a marker for other aspects of ALC differentiation. Our study examined the following on INSL3 peptide expression in ALC lineage (i) timing, (ii) which cell stage...
متن کاملAnion-templated self-assembly of tetrahedral cage complexes of cobalt(II) with bridging ligands containing two bidentate pyrazolyl-pyridine binding sites.
The bridging ligands L(1) and L(2) contain two N,N-bidentate pyrazolyl-pyridine units linked to a central aromatic spacer unit (1,2-phenyl or 2,3-naphthyl, respectively). Reaction with Ni(II) salts and treatment with the anions tetrafluoroborate or perchlorate result in formation of dinuclear complexes having a 2:3 metal:ligand ratio, with one bridging and two terminal tetradentate ligands. In ...
متن کاملMetallophilicity-assisted assembly of phosphine-based cage molecules.
A family of supramolecular cage molecules has been obtained via self-assembly of the phosphine-gold coordination complexes following an aurophilicity-driven aggregation approach. Use of the di- (PP) or tridentate (PPP) phosphine ligands Pn (n = 2, 3) with rigid polyaromatic backbones leads to clean formation of the coordination Pn(Au(tht))n(n+) species, sequential treatment of which with H2O/NE...
متن کاملNew Tetraaza Schiff Base Ligands and Their Complexes: Synthesis, Characterization and Thermodynamic Studies
Some new symmetrical tetraaza Schiff base ligands containing 2-quinolinecarboxaldehyde moiety formed from condensation reaction of 2-quinolinecarboxaldehyde and o-phenylenediamine derivatives, such as N, Nˊ-bis(2-quinolylmethylidene)-4-methoxy-1, 2-phenylenediimine (L1), N, Nˊ-bis(2-quinolylmethylidene)-4-methy-1, 2-phenylenediimine (L2), N, Nˊ-bis(2-quinolylmethylidene)-4-chloro-1, 2-phenylene...
متن کامل